Tetraaquabis(N,N-dimethylformamide-κO)zinc(II) bis[(2-{3-[2-(carboxylatomethoxy-κ2 O,O′)phenyl]pyrazol-1-yl-κN 2}acetato-κO)chloridozincate(II)]
نویسندگان
چکیده
The asymmetric unit of the title compound, [Zn(C(3)H(7)NO)(2)(H(2)O)(4)][Zn(C(13)H(10)N(2)O(5))Cl](2), is composed of a single anion and half a cation. The Zn(II) atom in the monoanion has a distorted triganol-pyramidal geometry, being coordinated by three O atoms and one N atom from one 2-{3-[2-(carboxyl-ato-meth-oxy)phen-yl]pyrazol-1-yl}acetate ligand and one Cl atom. In the dication, the Zn(II) atom is located on an inversion center and is coordinated by six O atoms in a slightly distorted octa-hedral geometry. In the crystal, the ions are linked by O-H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to the ab plane. There are also C-H⋯O and C-H⋯Cl inter-actions present, which lead to the formation of a three-dimensional structure.
منابع مشابه
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012